李洪基教授、王培龙副教授在Green Chemistry上发表论文

来源:biwn必赢 发布时间:2024-08-29 22:53:25 浏览次数: 【字体:

题目:Electrochemical N(sp2)–H/C(sp3)–H cross-coupling reaction between sulfoximines and alkylarenes

作者:Qing-Ru Zhu, Peng-Zhan Zhang, Xiang Sun, Hui Gao, Pei-Long Wang*, Hongji Li*

单位:Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; School of Chemistry and Materials Science, Huaibei, Anhui 235000, PR China

摘要:An electrochemical oxidation-induced amination of simple alkylarenes with sulfoximines as a nitrogen source and 5,6-dimethyl-1Hbenzo[d]imidazole as a catalyst under mild conditions was developed. This protocol represents a rare example of benzylic C–H functionalization of alkylarenes that involves the electrochemical generation of N-center radical, providing access to a range of corresponding aminated products in moderate to good yields.

影响因子:9.3

分区情况:一区

链接https://pubs.rsc.org/en/content/articlelanding/2024/gc/d4gc00191e


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